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GCSE & IGCSE chemistry practice

Titration calculations questions and answers

In a titration you add one solution from a burette until it exactly reacts with a measured volume of another. From the volumes and the known concentration you can work out the unknown concentration. The three steps: moles of the known solution, use the equation's ratio, then concentration = moles ÷ volume.

15 questions · Higher tier · Every answer is checked as you type it, with a full worked solution. Updated .

Where titration calculations comes up

GCSE (AQA)GCSE Chemistry only, Higher only: calculate an unknown concentration (or volume) from titration results. Titration is a required practical.
Cambridge IGCSE (0620)Supplement (Extended): use titration data to calculate the moles of solute, or the concentration or volume of a solution.

The method

  1. Mean titre: average the concordant results (within 0.10 cm³ of each other).
  2. Moles of the known solution = concentration × volume (dm³).
  3. Use the balanced equation's ratio to get the moles of the unknown.
  4. Unknown concentration = moles ÷ its volume (dm³).

Titration calculations questions

Try each one before looking at the hint. If you're stuck, the AI tutor can talk you through it step by step.

Warm-up

Question 1Warm-upHigher

Titres of 24.10, 24.20 and 24.15 cm³ were recorded. Calculate the mean titre.

Question 2Warm-upHigher

Titres of 25.60 (rough), 24.30, 24.40 and 24.35 cm³ were recorded. Using concordant results only, what is the mean titre?

Question 9Warm-upHigher

Titres of 22.50, 22.60 and 22.55 cm³ were recorded. Calculate the mean titre.

Question 10Warm-upHigher

How many moles of hydrochloric acid are in 18.0 cm³ of a 0.25 mol/dm³ solution?

Exam-style

Question 3Exam-styleHigher

25.0 cm³ of sodium hydroxide is neutralised by 20.0 cm³ of 0.10 mol/dm³ hydrochloric acid. NaOH+HCl→NaCl+H2O\text{NaOH} + \text{HCl} \rightarrow \text{NaCl} + \text{H}_2\text{O}. Calculate the concentration of the sodium hydroxide.

Question 4Exam-styleHigher

25.0 cm³ of 0.20 mol/dm³ sodium hydroxide is neutralised by 12.5 cm³ of hydrochloric acid. Calculate the concentration of the acid.

Question 5Exam-styleHigher

H2SO4+2NaOH→Na2SO4+2H2O\text{H}_2\text{SO}_4 + 2\text{NaOH} \rightarrow \text{Na}_2\text{SO}_4 + 2\text{H}_2\text{O}. 20.0 cm³ of 0.10 mol/dm³ sulfuric acid neutralises 25.0 cm³ of sodium hydroxide. Calculate the concentration of the sodium hydroxide.

Question 6Exam-styleHigher

What volume of 0.50 mol/dm³ hydrochloric acid neutralises 25.0 cm³ of 0.40 mol/dm³ sodium hydroxide? Give your answer in cm³.

Question 11Exam-styleHigher

25.0 cm³ of sodium hydroxide is neutralised by 15.0 cm³ of 0.20 mol/dm³ hydrochloric acid. Calculate the concentration of the sodium hydroxide. (NaOH+HCl→NaCl+H2O\text{NaOH} + \text{HCl} \rightarrow \text{NaCl} + \text{H}_2\text{O})

Question 12Exam-styleHigher

20.0 cm³ of 0.15 mol/dm³ sodium hydroxide is neutralised by 24.0 cm³ of hydrochloric acid. Calculate the concentration of the acid.

Question 13Exam-styleHigher

H2SO4+2NaOH→Na2SO4+2H2O\text{H}_2\text{SO}_4 + 2\text{NaOH} \rightarrow \text{Na}_2\text{SO}_4 + 2\text{H}_2\text{O}. 25.0 cm³ of 0.10 mol/dm³ sodium hydroxide is neutralised by 12.5 cm³ of sulfuric acid. Calculate the concentration of the acid.

Challenge

Question 7ChallengeHigher

In question 3, the sodium hydroxide's concentration was 0.08 mol/dm³. What is that in g/dm³? (NaOH: MrM_r = 40)

Question 8ChallengeHigher

Why is a few drops of indicator used rather than a large amount, and why is the burette read at the bottom of the meniscus?

Question 14ChallengeHigher

Sulfuric acid has a concentration of 0.25 mol/dm³. What is this in g/dm³? (MrM_r of H2SO4\text{H}_2\text{SO}_4 = 98)

Question 15ChallengeHigher

25.0 cm³ of potassium hydroxide is neutralised by 20.0 cm³ of 0.125 mol/dm³ nitric acid (KOH+HNO3→KNO3+H2O\text{KOH} + \text{HNO}_3 \rightarrow \text{KNO}_3 + \text{H}_2\text{O}). Calculate the concentration of the potassium hydroxide in g/dm³. (MrM_r of KOH = 56)

Common mistakes

  • Using volumes in cm³ in the moles calculation.
  • Ignoring a 1 : 2 ratio (e.g. H₂SO₄ with NaOH).
  • Including a rough or anomalous titre in the mean.

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Sources

The questions are our own. The “where it comes up” notes are from each board's published specification, checked on 27 October 2026:

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